I have been writing a 'manual' for vb.net 2010. It a student focused guide rather than a comprehensive book, and pretty basic, but if you want a copy I can pdf it to you. I am in the middle of ADO.net at the moment I would choose VB.net and C# as languages to learn. That would work on your existing skills and give you some modern skills. Once you get into the joy of classes you will see how good .net is.
If anyone wants a copy just send me a message and I pass back a dropbox link.