I don't know why that is, but you can remove that line - the project should still run. Try it.
In any case you can see the subroutine that sends an email -
Private Sub sendEmail
Dim mail As Email
mail.To.Add("somebody@somewhere.com")
mail.Subject = "New Subscription"
mail.Body = "Name = " & txtName.Text & "; Number = " & txtNumber.Text
' You can replace the line above with - mail.Body = "Name = A Name; Number = 0123-456789"
Dim intMsg As Intent = mail.GetIntent
StartActivity(intMsg)
End Sub
You can copy this into a project of your own. Note that you need to select the "Phone" library in the "Libraries" tab. That will show you how the process for sending an email works.
Try either of these things and let me know if you still get any problems. And let me know if it works, too.